Diversity of exophillic acid derivatives in strains of an endophytic Exophiala sp. Author Cheikh-Ali, Zakaria Merck Stiftungsprofessur für Molekulare Biotechnologie, Fachbereich Biowissenschaften, Goethe Universität Frankfurt, 60438 Frankfurt am Main, Germany Author Glynou, Kyriaki Author Ali, Tahir Author Ploch, Sebastian Author Kaiser, Marcel Author Thines, Marco Author Bode, Helge B. Author Maciá-Vicente, Jose G. text Phytochemistry 2015 2015-10-31 118 83 93 http://dx.doi.org/10.1016/j.phytochem.2015.08.006 journal article 10.1016/j.phytochem.2015.08.006 1873-3700 10488929

Table 1 NMR spectroscopic data (500 MHz, CD 3 OD) of compounds 19 and 20.

Position	Compound 19		Compound 20
	δ C	δ H (J in Hz)	δ C, mult.	δ H (J in Hz)
1			170.5 qC
2			113.5 qC
3			154.8 qC
4			112.2 CH	6.29, d (5.0)
5			149.4 qC
6			116.1 CH	6.57, d (5.0)
7			149.0 qC
8			37.9 CH2	2.89, m
				2.96, m
9			33.6 CH2	1.63, m
10			31.0 CH2	1.32, m
11			30.8 CH2	1.32, m
12			30.7 CH2	1.32, m
13			30.7 CH2	1.32, m
14			33.0 CH2	1.32, m
15			23.7 CH2	1.32, m
16			14.5 CH3	0.86, t (10.0)
10 (C=O)	172.6 qC		166.0 qC
20	118.2 qC		105.3 qC
30	160.6 qC		164.2 qC
40	102.2 CH	6.56, d (5.0)	102.0 CH	6.23, d (5.0)
50	157.5 qC		164.4 qC
60	111.7 CH	6.38, d (5.0)	109.1 CH	6.63, d (5.0)
70	144.3 qC		149.0 qC
80	34.9 CH2	2.55, m	36.8 CH2	2.89, m
		2.68, m		2.96, m
90	33.1 CH2	1.58, m	33.0 CH2	1.63, m
100	30.7 CH2	1.31, m	30.6 CH2	1.32, m
110	30.6 CH2	1.31, m	30.6 CH2	1.32, m
120	30.5 CH2	1.31, m	30.5 CH2	1.32, m
130	30.4 CH2	1.31, m	30.5 CH2	1.32, m
140	32.5 CH2	1.31, m	33.1 CH2	1.32, m
150	23.7 CH2	1.31, m	23.8 CH2	1.32, m
160	14.4 CH3	0.9, t (10.0)	14.5 CH3	0.89, t (10.0)
100	103.6 CH	4.85, d (7.5)
200	75.0 CH	3.47, t (7.5)
300	77.7 CH	3.44, m
400	71.2 CH	3.40, m
500	78.3 CH	3.42, ddd (2.0, 5.5, 7.5)
600	62.5 CH2	3.72, d/d (5.0, 10.0)
		3.90, d/d (1.5, 10.0)