Sesquiterpenoids and monoterpenoids from the water decoction of Valeriana officinalis L Author Li, Shi-Wei , Bian-Xia Xue &, Tian-Tian Yang &, Ran Li &, Mingjie Zhang &, &, Peng Zhang &, Yi Zhang &, Tao Wang &, Shao-Xia Wang & * & State Key Laboratory of Component-based Chinese Medicine, Institute of Traditional Chinese Medicine, Tianjin University of Traditional Chinese Medicine, 10 Poyanghu &, Bian-Xia Xue &, Tian-Tian Yang &, Ran Li Author Xue, Bian-Xia Author Yang, Tian-Tian Author Li, Ran Author Zhang, Mingjie Author Wang, Miao Author Zhang, Li-Hua Author Zhang, Peng Author Zhang, Yi Author Wang, Tao Author Wang, Shao-Xia Author Wu, Hong-Hua text Phytochemistry 2023 113474 2023-01-31 205 1 11 http://dx.doi.org/10.1016/j.phytochem.2022.113474 journal article 10.1016/j.phytochem.2022.113474 1873-3700 8194509

Table 3 NMR data for 7.

position	δ (J in Hz) a H	δ type b C,	HMBC
a Measured at 600 MHz in CD OD; 3 b Measured at 150 MHz in CD OD.
1	2.06, d (2.4)	54.6, CH	3, 4, 5
2	–	159.3, C	–
3	3.92, d (1.8)	88.0, CH	1, 2, 5, 7, 1′
4	2.09, d (3.0)	51.7, CH	1, 2, 3, 6
5	1.16, m, 1.85, m	26.4, CH2	1, 3, 6, 7
6	1.19, m, 1.86, m	28.1, CH2	1, 2, 5, 7
7	–	46.7, C	–
8	5.13, t (1.5), 5.03, s	108.1, CH2	1, 2, 3
9	1.12, s	23.6, CH3	1, 4, 7, 10
10	0.97, s	22.1, CH3	1, 4, 7, 9
1′	4.38, d (7.8)	105.8, CH	3, 3′, 5′
2′	3.17, dd (9.2, 7.8)	75.4, CH	1′, 3′, 4′
3′	3.34, t (9.0)	78.0, CH	2′, 4′
4′	3.27, t (9.0)	71.8, CH	3′, 6′
5′	3.39, ddd (8.4, 6.2, 2.0)	76.7, CH	1′, 3′, 4′
6′	3.61, dd (10.8, 6.0)	68.6, CH2	5′, 1′′
	3.96, dd (10.8, 1.8)
1′′	5.01, d (2.1)	110.8, CH	6′, 2′′, 3′′
2′′	3.89, d (2.4)	78.2, CH	1′′, 4′′, 5′′
3′′	–	80.6, C	–
4′′	3.77, d (9.6),	75.1, CH2	2′′, 3′′, 5′′
	3.95, d (9.6)
5′′	3.59, s	65.9, CH2	2′′, 3′′, 4′′