Sesquiterpenoids and monoterpenoids from the water decoction of Valeriana officinalis L Author Li, Shi-Wei , Bian-Xia Xue &, Tian-Tian Yang &, Ran Li &, Mingjie Zhang &, &, Peng Zhang &, Yi Zhang &, Tao Wang &, Shao-Xia Wang & * & State Key Laboratory of Component-based Chinese Medicine, Institute of Traditional Chinese Medicine, Tianjin University of Traditional Chinese Medicine, 10 Poyanghu &, Bian-Xia Xue &, Tian-Tian Yang &, Ran Li Author Xue, Bian-Xia Author Yang, Tian-Tian Author Li, Ran Author Zhang, Mingjie Author Wang, Miao Author Zhang, Li-Hua Author Zhang, Peng Author Zhang, Yi Author Wang, Tao Author Wang, Shao-Xia Author Wu, Hong-Hua text Phytochemistry 2023 113474 2023-01-31 205 1 11 http://dx.doi.org/10.1016/j.phytochem.2022.113474 journal article 10.1016/j.phytochem.2022.113474 1873-3700 8194509

Table 4 NMR data for 8.

position	δ (J in Hz) a H	δ type b C,	HMBC
a Measured at 600 MHz in CD OD; b Measured at 150 MHz in CD OD.
a Measured at 600 MHz in CD OD; 3 b Measured at 150 MHz in CD OD.
1	–	138.8, C	–
2	–	166.7, C	–
3	4.77, t (7.2)	80.1, CH	1, 5, 10
4	3.98, d (8.1)	40.4, CH	1, 5, 7, 9
5	1.97, dd (9.0, 7.2)	40.6, CH2	1, 2, 3, 4, 7
	2.00, dd (7.2, 3.6)
6	10.05, s	190.3, CH	1, 5
7	–	152.9, C	–
8	9.59, s	195.7, CH	4, 7, 9
9	5.99, d (3.4)	133.9, CH2	4, 7, 8
10	2.25, s	11.5, CH3	1, 2, 3
1	–	180.8, C	–
2	2.44, t (7.0)	32.7, CH2	3, 4
3	2.75, t (7.0)	39.9, CH2	1, 4, 5
4	–	211.1, C	–
5	3.12, m	33.1, CH2	4, 6, 7
6	2.90, t (6.4)	36.9, CH2	7
7	–	189.9, C	–
8	–	153.8, C	–
9	7.34, dd (3.6, 0.6)	118.8, CH	8, 11
10	6.63, dd (3.6, 1.7)	113.3, CH	–
11	7.75, s	148.3, CH	8, 9